Effect of cement temperature on the performance of pce powder

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Since 2022, Russia-Ukraine geopolitical conflicts have intensified, and global energy prices have risen sharply, with international natural gas prices hitting historic highs. As the most important transitional energy source in the transition from fossil energy to non-fossil energy, the share of natural gas in primary energy has increased from 14.6% in 1965 to 24.7% in 2020.  The global gas price indices showed a unilateral downward trend from 2018, bottomed out in 2020, and remained low for a long time. However, since July 2020, the global gas prices have gradually fluctuated upward, and the impact of geopolitical events made the Dutch TTF gas price even hit record highs repeatedly.

An analyst of a securities company believes that the core catalyst of this round of global gas market lies in the lack of investment in upstream oil and gas resources caused by long-term low prices. Since 2020, although the epidemic has led to a decline in demand, the decline in supply has been faster, resulting in a large inventory consumption. In 2021, demand will recover faster than supply (the supply-side is less sensitive to prices, which will be reflected in investment).  

As the world's two largest gas pce powder are also expected to change significantly.

If the compatibility of polycarboxylate superplasticizer and cement is not good, the concrete mixture is prone to some problems, such as segregation, bleeding, greater slump loss, shorter setting time and so on, so that the concrete mixture can not be transported and poured normally. Reduce the strength and durability of concrete.

There are many factors affecting the compatibility of cement and superplasticizer, and the cement storage temperature is a key factor that can not be ignored. If the cement storage temperature is too high during concrete mixing, it will directly affect the physical and mechanical properties of cement.

Effect of cement temperature on the performance of concrete mixture:

When the cement temperature is above 60 ℃, a small amount of water is secreted from the concrete mixture. When the cement temperature is 100 ℃, the aggregate is separated from the paste, and the cohesion of the concrete mixture becomes worse. The reason for this negative effect is that the cement temperature is high, which makes the concrete mixture temperature rise rapidly in a short time. It is easier to stimulate the water-reducing function of polycarboxylic acid high-performance superplasticizer, release more free water wrapped in the mixture particles in the case of high temperature, and make a small amount of water bleeding in the concrete outlet.

Effect of cement temperature on setting time of concrete:

With the decrease of cement temperature, the setting time of concrete is prolonged, and the initial setting time is more obvious than the final setting time. In other words, the higher the cement temperature, the shorter the setting time of concrete. The reasons for the shortening of setting time caused by high temperature cement are as follows: (1) it will increase the temperature of the mixture in a short time and promote the hydration of cement particles; (2) the superplasticizer releases more free water to react with cement particles, thus forming a stable cementitious system in a shorter time.

With the passage of time, the heat contained in cement temperature is easily transferred to the surrounding particles or environment, the temperature of concrete system gradually approaches to the ambient temperature, and the temperature gap of concrete mixed with cement at different temperatures is gradually narrow. as a result, the difference of the final setting time of concrete is relatively reduced.

Effect of cement temperature on slump and air content loss of concrete:

At the same time, the higher the cement temperature is, the greater the slump loss rate is. The difference of slump loss rate under different temperature conditions increases at first and then decreases. Under the condition of the same slump loss rate, the lower the cement temperature is, the longer it takes to reach the slump loss rate, that is to say, the more beneficial to reflect the slump-retaining performance of the superplasticizer. When the cement temperature is high, in order to reduce the slump loss of concrete, it is necessary to put forward higher requirements for the slump retention of superplasticizer.

Summary,

1. For the concrete with the same mix ratio, with the increase of cement temperature, the adaptability of admixture and cement becomes worse. The higher the temperature is, the more water is consumed, and the fluidity of concrete mixture decreases, resulting in the decrease of concrete and workability. It even leads to the separation or bleeding of aggregate and paste.

2. The higher the cement temperature, the worse the adaptability of cement and superplasticizer, the greater the loss rate of slump and air content, and the shorter the setting time of concrete.

3. The effect of the change of cement temperature on the compressive strength of concrete is obvious. with the increase of cement temperature, the compressive strength of low heat cement concrete increases in the early stage (before 7 days), but the compressive strength of 28 days decreases with the increase of temperature.

4. It is suggested that the cement temperature for concrete mixing should not exceed 60 ℃. When it exceeds 60 ℃, the concrete production system should precool the raw materials of the mixing system as far as possible to avoid excessive temperature rise of the whole mixture system due to high cement temperature. and should strengthen the maintenance of the concrete after entering the warehouse to avoid the temperature cracks caused by the early hydration temperature rising too fast.

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The UAE is the gateway to the Middle East, North Africa, Central Asia, and sub-Saharan Africa, said Subramaniam, a senior official at India's Ministry of Commerce and Industry.  The agreement will help boost bilateral trade in goods from $60 billion a year now to $100 billion a year within five years.

On 18 February 2022, India and the United Arab Emirates signed the Comprehensive Economic Partnership Agreement. With the entry into force of the agreement, 90 percent of Indian goods and 65 percent of UAE goods will enjoy tariff-free market access.

Apart from its FTA with the UAE, India is also pursuing FTAs with Australia, the UK, Canada, Israel, the European Union, and the Gulf Cooperation Council.

Influenced by international situations, the supply and prices of many pce powder are still very uncertain.

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